Views: 1000 Author: Site Editor Publish Time: 2024-11-19 Origin: Site
The preparation of cellulose nanocomposite coatings mainly relies on the high specific surface area and surface activity of nanocellulose , which can form a uniform dispersion system with various functional materials (such as polymers, metal oxides or carbon-based materials) through specific The coating technology prepares composite coatings to ultimately achieve the required functionality (such as barrier properties, antibacterial properties, electrical conductivity, etc.).
1. Preparation steps of cellulose nanocomposite coating
1. Material preparation
Nanocellulose raw materials: Cellulose nanocrystals (CNCs), cellulose nanofibers (CNFs) or bacterial cellulose (BC), and their form and purity can be selected according to their needs.
Functional materials: Select functional additives according to the specific application, such as:
Polymers (PVA, PLA, epoxy resin, etc.) enhance adhesion and mechanical properties;
Inorganic nanoparticles (TiO₂, ZnO, SiO₂) improve barrier properties, antibacterial properties or optical properties;
Graphene/carbon nanotubes impart electrical conductivity and thermal conductivity;
Other functional components (such as dyes, catalysts, flame retardants, etc.).
2. Preparation of nanocellulose dispersion
Dispersion step: The nanocellulose is prepared into a uniform dispersion liquid by ultrasonic dispersion or high-speed stirring. Deionized water or a solution containing a dispersant is usually used as the medium.
If functional modification is required, surf modifiers (such as hydrophobic agents, surfactants, etc.) can be added to improve the compatibility of cellulose nanoparticles with other materials.
3. Prepare nanocomposite coating solution
Add functional materials (such as inorganic nanoparticles, polymer solutions or other enhancers) to the cellulose nanodispersion in proportion.
Use magnetic stirrers, ultrasonic or high-speed dispersion equipment to ensure that all ingredients are evenly distributed to form a stable composite coating solution.
If the functional material is difficult to dissolve, solvents can be used to assist (such as ethanol, water-alcohol mixed solvents).
4. Choice of coating technology
Select the appropriate coating method according to the coating application scenario:
① Spin Coating method: Add the composite coating solution dropwise to the surface of the substrate and apply evenly through high-speed rotation.
Suitable for high-precision needs such as thin film electronic materials and optical coatings.
② Dip Coating method: immerse the substrate in the composite coating solution, and then slowly remove it to form a uniform coating.
Suitable for coatings of complex shapes or large areas of substrates.
③Spray Coating: Use a spray gun to spray the composite coating evenly on the surface of the substrate.
Commonly used in industrial coatings and large-area coatings.
④ Blade Coating method: Use a scraper to evenly apply the paint to the substrate to control the thickness.
Applied to the preparation of thick film coatings.
5. Curing and drying of the coating
Natural drying: Dry at room temperature, suitable for heat-sensitive scenes to substrates.
Thermal curing: Place the coated substrate in an oven, usually heated at 50-120°C for several hours to ensure uniform curing of the coating.
UV curing: For coatings containing photosensitive materials, ultraviolet curing can be used to improve efficiency.
6. Coating performance optimization (optional steps)
Post-treatment: such as hot pressing of coatings, surface polishing or multi-layer coating stacking to enhance performance.
Performance testing: Verify that the functionality of the coating meets the design requirements by testing mechanical properties (such as strength, toughness), barrier properties (such as gas/moisture barrier), optical properties or electrical conductivity.
2. Application cases of cellulose nanocomposite coating
Barrier Coating: Nanocellulose composite graphene oxide coating provides excellent gas and moisture barrier properties in food packaging, extending food shelf life.
Antibacterial coating: An antibacterial coating prepared by combining nanocellulose with nanoparticles such as ZnO and Ag, can be used in the surfaces of medical devices and protective equipment.
Conductive coating: Nanocellulose coatings have been used in flexible electronic devices and sensor fields by introducing graphene or carbon nanotubes.
Anticorrosion coating: Nanocellulose composite materials can improve corrosion resistance after coating on metal surfaces and are widely used in marine engineering and construction fields.
Cellulose nanocomposite coating combines the high strength, high specific surface area and special properties of nanocellulose, and can prepare high-performance coatings that meet different needs through a variety of coating methods. In the future, with the further development of nanocellulose technology and the cost decrease, its application potential in environmentally friendly packaging, medical care, electronics and energy fields will be further released, bringing more possibilities to the development of green materials.